Ipzz-266 Updated Link

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    2.3. Suzuki–Miyaura Polymerization to Form P3HT‑Backbone (Polymer A)

    Polymer A was obtained by coupling Monomer 1 (5 mmol) with 2,5‑bis(pinacolborane)‑3‑hexylthiophene (5 mmol) using Pd(OAc)₂ (0.05 mmol) and TFP (0.10 mmol) in a 1:1 mixture of THF/DMF (100 mL) with K₂CO₃ (10 mmol) as base. The reaction proceeded at 90 °C for 48 h under N₂. After work‑up and precipitation into methanol, Gel‑Permeation Chromatography (GPC, THF, polystyrene standards) indicated Mₙ = 28 kDa, Đ ≈ 1.12. Steps to Find Information:

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